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What network were these people IMing you on? You can try changing your privacy settings to allow for only people on your contact list to talk to you.
Trillian doesn't use any registry settings, so you can just copy the install directory (Likely c:\program files\trillian) to the new computer, and create a link that points to trillian.exe. The file that keeps your contact aliasing information is (install directory)\users\default\buddies.xml, if you have a single user setup. If you don't know or can't find it, just search for buddies.xml.
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